930608-64-3

Basic information

• Product Name: 3-((R)-hex-1-yn-3-yloxy)phenyl acetate
• Synonyms: 3-((R)-hex-1-yn-3-yloxy)phenyl acetate
• CAS NO: 930608-64-3
• Molecular Weight: 232.279
• Mol File: 930608-64-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-((R)-hex-1-yn-3-yloxy)phenyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 3-((R)-hex-1-yn-3-yloxy)phenyl acetate(930608-64-3)
• EPA Substance Registry System: 3-((R)-hex-1-yn-3-yloxy)phenyl acetate(930608-64-3)

Safety Data

• Hazardous Substances Data: 930608-64-3(Hazardous Substances Data)

Upstream product

• 689-00-9 hex-1-yn-3-one 
• 102-29-4 Resorcinol monoacetate 
• 105-31-7 (S)-(-)-1-hexyn-3-ol 

Relevant articles and documents

Catalytic asymmetric synthesis of allylic aryl ethers

(Chemical Equation Presented) The reaction of trichloroacetimidate derivatives of (Z)-2-alken-1-ols with phenol nucleophiles in the presence of the palladium(II) catalyst [COP-OAc]2 provides 3-aryloxy-1-alkenes in high yields and high enantiomeric purity (typically 63-90% yield and 90-97% ee). The reaction is exemplified by 20 examples. The method employs 1 mol % of the commercially available catalysts (S)- or (R)-[COPOAc]2, produces the branched isomer with unprecedented regioselectivity, and is compatible with the presence of base-labile functionality in either reactant.