93079-31-3

Upstream product

• 93079-23-3 (2R,3R)-3-O-benzyl-tridecane-1,2,3-triol 
• 93079-30-2 (2R,3R)-1,2-epoxy-3-O-benzyl-tridecan-3-ol 
• 626-88-0 1-bromo-5-methylpentane 
• 93079-24-4 C₂₇H₄₀O₅S 
• 1346258-48-7 (2R,3R)-1,2-O-cyclohexylidene-3-O-benzyl-tridecane-1,2,3-triol 
• 654077-23-3 (2R)-1,2-(cyclohexylidenedioxy)tridecan-3-one 

Downstream Products

• 936650-26-9 (11R,12R)-12-(tert-butyldimethylsilyloxy)-17-methyloctadecan-11-yl-4-methylbenzenesulfonate 
• 54910-51-9 (2S-cis)-7,8-epoxy-2-methyloctadecane 
• 1346258-54-5 C₃₂H₆₀O₂Si 

Relevant academic research and scientific papers

An enantiodivergent synthesis of both (+)- and (-)-disparlure from (R)-2,3-cyclohexylideneglyceraldehyde

Reduction of ketone 3 derived from (R)-2,3-cyclohexylideneglyceraldehyde 1 with some common hydrides took place with syn-selectivity. The resulting major product 4a has been exploited as a common chiral template to prepare both enantiomers Ia,b of disparlure.