93098-86-3Relevant academic research and scientific papers
2-Cyclopropylidene-1,3-cycloalkanediones as Intermediates in a Nucleophilic Substitution at a Three Membered Ring
Weidner, Juergen,Vilsmaier, Elmar,Fries, Ralf
, p. 1039 - 1056 (2007/10/02)
Reaction of morpholinobicycloalkyl-dimedone 4C with various CH-acids 3 leads to a substitution of the exo-dimedone unit as a consequence of a strong preference of the exo-leaving group in a bicyclic compound of type 4 and 5, respectively.Dimedone (3C) as
Reactions with Aminobicycloalkanes, I - Thermolysis of Aminobicycloalkanes with a Dimedone Moiety
Vilsmaier, Elmar,Joerg, Klaus
, p. 2910 - 2927 (2007/10/02)
From the bicyclic aminals 4 and dimedone (5) derivatives 6 are obtained, which give different types of products upon thermolysis depending on the ring size of the bicyclus.The bicycloheptane and -octane compounds 6b,c lead to diacylated enamines 8b,c by p
