93110-72-6

Basic information

• Product Name: P(C₆H₅)4⁽¹⁺⁾*MnFe₃(CO)13C^(1-) = [P(C₆H₅)4][MnFe₃(CO)13C]
• CAS NO: 93110-72-6
• Molecular Weight: 938.022
• Mol File: 93110-72-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: P(C₆H₅)4⁽¹⁺⁾*MnFe₃(CO)13C^(1-) = [P(C₆H₅)4][MnFe₃(CO)13C](CAS DataBase Reference)
• NIST Chemistry Reference: P(C₆H₅)4⁽¹⁺⁾*MnFe₃(CO)13C^(1-) = [P(C₆H₅)4][MnFe₃(CO)13C](93110-72-6)
• EPA Substance Registry System: P(C₆H₅)4⁽¹⁺⁾*MnFe₃(CO)13C^(1-) = [P(C₆H₅)4][MnFe₃(CO)13C](93110-72-6)

Safety Data

• Hazardous Substances Data: 93110-72-6(Hazardous Substances Data)

Upstream product

• 37504-44-2 (acetonitrile)pentacarbonylmanganese(I) hexafluorophosphate 
• 93110-67-9 2P(C₆H₅)4⁽¹⁺⁾*Fe₃(CO)9(CCO)^(2-) = [P(C₆H₅)4]2[Fe₃(CO)9(CCO)] 

Relevant articles and documents

Syntheses of reactive mixed-metal carbide clusters and their interaction with proton sources

The three-iron ketenylidene [Fe3(CO)9(CCO)]2-, I, undergoes a redox condensation reaction with [Rh-(CO)2Cl]2 to produce a reactive butterfly carbide [RhFe3(CO)12C]-, VIII. Similarly, I in the prescence of [Mn(CO)5(CH3CN)]+ leads to [MnFe3(CO)13C]-, IX. Both products were characterized by 13C NMR spectroscopy, and the structure of the rhodium cluster VIII was determined by single-crystal X-ray diffraction. Monoprotonation of VIII and IX yields the butterfly methylidynes RhFe3(CO)12(CH), XII, and MnFe3-(CO)13(CH), XIII. This site of protonation contrasts with the butterfly carbide [Fe4(CO)12C]2-, II, which first protonates on the metal framework. In some cases the redox condensation reaction does not terminate at the four-metal butterfly cluster stage, thus the reaction of I with [CpNi(CO)]2 yields [Ni3Fe3(CO)13C]2-, X. Attempts to generate a butterfly carbide via a metal substitution pathway employing II and Co2(CO)8 did not lead to a tetranuclear cluster but produced instead the pentanuclear carbide [CoFe4(CO)14C]-, XI, the structure of which was also determined by single-crystal X-ray diffraction. X-ray crystal data for [PPN][RhFe3(CO)12C]·CH2Cl2, VIII: orthorhombic, a = 17.780 (2) A?, b = 19.641 (4) A?, c = 15.145 (4) A?, Z = 4, space group Pna21. For [PPN][CoFe4(CO)14C], XI: monoclinic, a = 17.403 (3) A?, b = 16.030 (3) A?, c = 19.055 (2) A?, β= 105.34 (1)°, Z = 4, space group P21/n.