931103-80-9

Upstream product

• 518316-74-0 (4R,6S)-4-[(tert-butyldimethylsilyl)oxy]-6-methyl-2-cyclohexenone 
• 182184-47-0 [4S,5S,(S)R]-4-hydroxy-5-methyl-4-[(p-tolylsulfinyl)methyl]-2-cyclohexenone 
• 1351594-97-2 (S)-4,4-dimethoxy-5-methylcyclohex-2-enone 
• 518316-73-9 (1S,4R,6S)-4-[(tert-butyldimethylsilyl)oxy]-6-methyl-1-[(p-tolylsulfonyl)methyl]cyclohex-2-en-1-ol 
• 518316-72-8 (1S,4R,6S)-6-methyl-1-[(p-tolylsulfonyl)methyl]cyclohex-2-ene-1,4-diol 
• 518316-68-2 (4S,5S)-4-hydroxy-5-methyl-4-[(p-tolylsulfonyl)methyl]cyclohex-2-enone 

Downstream Products

• 1123211-33-5 C₁₇H₁₇F₃O₄ 
• 1123211-32-4 C₁₇H₁₇F₃O₄ 

Relevant academic research and scientific papers

A stereoselective approach to functionalized cyclohexenones

A catalytic enantioselective approach to 4-hydroxy-6-methylcyclohex-2- enones is presented herein. The stereogenic information is generated through a copper-catalyzed 1,4-addition to p-benzoquinone monoketal using a chiral, BINOL-based (BINOL = 1,1′-bi-2-

Enantioselective synthesis of natural polyoxygenated cyclohexanes and cyclohexenes from [(p-tolylsulfinyl)methyl]-p-quinols

Exploitation of the β-hydroxysulfoxide fragment present in a number of enantiomerically pure (SR)and (SS)-[(p-tolylsulfinyl)methyl]-pquinols allowed chemo- and stereocontrolled conjugate additions of different organoaluminium reagents to the cyclohexadien