93125-48-5

Upstream product

• 124290-99-9 (4S,5R)-5-((trityloxy)methyl)tetrahydrofuran-2,4-diol 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 116444-21-4 (2-deoxy-5-O-triphenylmethyl-α-D-erythro-pentofuranosyl)iodomethane 
• 116444-21-4 (2-deoxy-5-O-triphenylmethyl-β-D-erythro-pentofuranosyl)iodomethane 

Relevant academic research and scientific papers

SYNTHESIS OF C-GLYCOSYL COMPOUNDS BY THE WITTIG IODOCYCLIZATION PROCEDURE. DIFFERENCES FROM MERCURIOCYCLIZATION

Various sugars were C-glycosylated by treatment with methylenetriphenylphosphorane and subsequent iodocyclization of the resulting hept- and hex-enitols.In all cases, a C-glycofuranosyl compound was obtained, except for 3,4,5,7-tetra-O-benzyl-1,2-dideoxy-

Stereochemistry of C-glycosidation through a Wittig-mercuriocyclization Procedure

The stereochemistry of C-glycosidation by reaction of the aldehydo group of the carbohydrate with methylenetriphenylphosphorane, and subsequent mercuriocyclization of the obtained product, has been investigated on different substrates.The procedure is ste