93172-19-1Relevant academic research and scientific papers
Substituent Effects on the Acid-catalyzed Isomerization of 2-Cyclohepta-2,4,6-trienyltropone Derivatives to 2-Benzyltropones
Miyano, Hiroyuki,Nitta, Makoto
, p. 999 - 1004 (2007/10/02)
The acid-catalyzed isomerization of the cycloheptatriene ring of 2-cyclohepta-2,4,6-trienyltropones to give benzyltropones via the norcaradiene intermediate has been studied.In the cases of 7-substituted 2-cyclohepta-2,4,6-trienyltropones (1a-f), the firs
PHOTOCHEMICAL REACTIONS OF DIALKYLBORYLTROPOLONATE COMPLEXES
Okada, Keiji,Inokawa, Haruki,Oda, Masaji
, p. 4395 - 4398 (2007/10/02)
Irradation of a benzene solution of dialkylboryltropolonates produced alkyl migrated tropolone and tropone derivatives.The product distribution and the mechanism of this rearrangement were investigated.
A Radical-induced Extrusion Reaction of 2-(Benzylsulfonyl)tropones to 2- and 4-Benzyltropones
Takeshita, Hitoshi,Matsuo, Norihide,Mametsuka, Hiroaki
, p. 2321 - 2322 (2007/10/02)
Several 2-(benzylsulfonyl)tropones were thermolized to give 2- and 4-benzyltropones.The radical mechanism for the thermolysis was elucidated by a deuterium-labelling experiment.
