93175-56-5

Basic information

• Product Name: Cyclohexanone, 3-heptyl-
• CAS NO: 93175-56-5
• Molecular Formula: C13H24O
• Molecular Weight: 196.333
• Mol File: 93175-56-5.mol

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 3-heptyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 3-heptyl-(93175-56-5)
• EPA Substance Registry System: Cyclohexanone, 3-heptyl-(93175-56-5)

Safety Data

• Hazardous Substances Data: 93175-56-5(Hazardous Substances Data)

Upstream product

• 930-68-7 cyclohexenone 
• 629-04-9 1-Bromoheptane 
• 110-91-8 morpholine 
• 629-06-1 1-Chloroheptane 

Relevant articles and documents

3-Metallated enamines XI. Transmetallation of 3-Stannylated enamines - A new method to generate 1-aminoallyllithium compounds

The transmetallation of 3-stannylated enamines, 1-morpholino-3-(trialkylstannyl)cycloalk-1-enes and 3-morpholino-5-(tributylstannyl)hex-3-ene, with butyllithium is a new and general way to generate s1-aminoallyllithium compounds. Stabilization by aromatic substituents is not further necessarily as in the case of preparation by deprotonation and even the thermodynamically less stable exoamino derivatives are accessible. Therefore homoenolate-equivalents of cyclic ketones are made available. Thus, the corresponding 3-alkylated or 3-silylated cycloalkanones and alken-3-ones were prepared via the 1-morpholinoallyllithium compounds.

Ultrasound in Organic Synthesis. 7. Preparation of Organozinc Reagents and Their Nickel-Catalyzed Reactions with α,β-Unsaturated Carbonyl Compounds

Diorganozinc compounds can be prepared with great ease and efficiency in a one-pot process, by sonication of lithium, an organic halide, and a zinc halide in THF or toluene mixtures.The reagents thus obtained give rise to clean and selective conjugate additions to α,β-unsaturated aldehydes and ketones in the presence of catalytic amounts of nickel acetylacetonate.

ULTRASOUND IN ORGANIC SYNTHESIS 6. AN EASY PREPARATION OF ORGANOZINC REAGENTS AND THEIR CONJUGATE ADDITION TO α-ENONES

Sonication allows the efficient preparation of various organozinc reagents, which cleanly add in a conjugate fashion to α-enones in the presence of Ni(acac)2.