93183-63-2

Basic information

• Product Name: Octane, 1-(methylsulfinyl)-, (R)-
• CAS NO: 93183-63-2
• Molecular Formula: C9H20OS
• Molecular Weight: 176.323
• Mol File: 93183-63-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Octane, 1-(methylsulfinyl)-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Octane, 1-(methylsulfinyl)-, (R)-(93183-63-2)
• EPA Substance Registry System: Octane, 1-(methylsulfinyl)-, (R)-(93183-63-2)

Safety Data

• Hazardous Substances Data: 93183-63-2(Hazardous Substances Data)

Upstream product

• 3079-27-4 methyl n-octylsulfoxide 
• 3698-95-1 methyl octyl sulfide 

Relevant articles and documents

Solid State Kinetic Resolution of β-Ionone Epoxide and Dialkyl Sulphoxides in the Presence of Optically Active Host Compounds. The First Enantioselective Host-Guest Inclusion Complexation in the Solid State

Kinetic resolution of β-ionone epoxide and some dialkyl sulphoxides is achieved in the solid state in the presence of an optically active host compound, and is confirmed to proceed via a combination process of enantioselective inclusion complexation and selective oxidation in the solid state; enantioselective complexation in the solid state is also observed for oximes.

SYNTHESIS OF CHIRAL SULFOXIDES BY ASYMMETRIC OXIDATION

The main chemical or enzymatic methods of asymmetric oxidation of sulfides are reviewed.A new approach to chiral sulfoxides is described, which uses tertiobutyl hydroperoxide in presence of a chiral titanium complex.The results obtained during the last two years are summarized.The best enantiomeric excess amounts to 95percent in the case of formation of cyclopropyl phenyl sulfoxide.