93215-55-5

Basic information

• Product Name: 2'-(3,6-di-O-acetyl-4-deoxy-β-D-glycero-hex-3-enopyranosyl-2-ulose)acetophenone
• Synonyms: 2'-(3,6-di-O-acetyl-4-deoxy-β-D-glycero-hex-3-enopyranosyl-2-ulose)acetophenone
• CAS NO: 93215-55-5
• Molecular Weight: 346.337
• Mol File: 93215-55-5.mol

Chemical Properties

• CAS DataBase Reference: 2'-(3,6-di-O-acetyl-4-deoxy-β-D-glycero-hex-3-enopyranosyl-2-ulose)acetophenone(CAS DataBase Reference)
• NIST Chemistry Reference: 2'-(3,6-di-O-acetyl-4-deoxy-β-D-glycero-hex-3-enopyranosyl-2-ulose)acetophenone(93215-55-5)
• EPA Substance Registry System: 2'-(3,6-di-O-acetyl-4-deoxy-β-D-glycero-hex-3-enopyranosyl-2-ulose)acetophenone(93215-55-5)

Safety Data

• Hazardous Substances Data: 93215-55-5(Hazardous Substances Data)

Upstream product

• 13735-81-4 1-styrenyloxytrimethylsilane 
• 41107-22-6 (2R,3R)‐3,5‐diacetoxy‐2‐(acetoxymethyl)‐2,3‐dihydro‐4H‐pyran‐4‐one 

Relevant articles and documents

STEREOSELEKTIVE C-GLYCOSIDSYNTHESE DURCH TITAN-(IV)-KATALYSIERTE ADDITION VON SILYLENOLETHERN AN 2-ACYLOXY-3-KETO-GLYCALE

C-Glycosides are stereoselectively formed by the titan-(IV)-catalysed addition of silyl enolethers 2 to 2,4,6-tri-O-acyl-1-deoxy-D-erythro-hex-1-enopyran-3-uloses 1 followed by elimination of the 4-acyloxy substituent.Cyclohexenyl silylether 2a reacts wit

STEREOSELECTIVE SYNTHESIS OF C-GLYCOSYL COMPOUNDS via MICHAEL ADDITION OF TRIMETHYLSILYL ENOL ETHERS AND ENAMINES TO HEX-1-ENOPYRAN-3-ULOSES

The titanium(IV)-catalyzed addition of trimethylsilyl enol ethers to 2,4,6-tri-O-acylhex-1-enopyran-3-uloses (3 and 4) gave stereoselectively 3,6-di-O-acyl-4-deoxy-β-D-glycero-hex-3-enopyranosyl-2-ulose derivatives.The formation of the C-glycosyl bond was