93221-57-9

Upstream product

• 93178-07-5 (S)-[(1R,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-1-methyl-2-methylene-cyclopentyl]-((R)-5-isopropyl-2-methyl-cyclopent-1-enyl)-methanol 
• 93178-07-5 (R)-[(1R,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-1-methyl-2-methylene-cyclopentyl]-((R)-5-isopropyl-2-methyl-cyclopent-1-enyl)-methanol 
• 105576-35-0 (+)-3(S)-isopropyl-1-methyl-2-(hydroxymethyl)cyclopent-1-ene 
• 56198-86-8 (R)-3-isopropyl-2-methoxycarbonyl-1-methyl-cyclopentene 
• 56198-86-8 (S)-3-isopropyl-2-methoxycarbonyl-1-methyl-cyclopentene 
• 107398-14-1 L-menthyl (3R)-1-iriden-7-oate 
• 93177-94-7 2-[(S)-5-((R)-2-Benzyloxy-1-methyl-ethyl)-2-methyl-cyclopent-1-enyl]-[1,3]dioxolane 
• 107439-80-5 (3S,8R)-7,7-ethylenedioxy-1-iriden-9-ol 
• 107439-79-2 2-((S)-5-Isopropenyl-2-methyl-cyclopent-1-enyl)-[1,3]dioxolane 
• 85720-03-2 l-menthyl (S)-1-methyl-3-isopropenylcyclopentene-2-carboxylate 
• 85761-25-7 (5S)-1-hydroxymethyl-2-methyl-5-(1-methylethenyl)-1-cyclopentene 
• 38231-11-7 (5S)-1-formyl-2-methyl-5-(1-methylethenyl)-1-cyclopentene 
• 107398-15-2 (-)-1-methyl-2-(hydroxymethyl)-3(R)-isopropylcyclopentene 

Downstream Products

• 93178-07-5 (S)-[(1R,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-1-methyl-2-methylene-cyclopentyl]-((R)-5-isopropyl-2-methyl-cyclopent-1-enyl)-methanol 
• 93178-07-5 (R)-[(1R,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-1-methyl-2-methylene-cyclopentyl]-((R)-5-isopropyl-2-methyl-cyclopent-1-enyl)-methanol 

Relevant academic research and scientific papers

Synthetic Photochemistry. XXXIV. Synthetic Strategy of 5-8-5-Membered Tricyclic Higher Terpenoids Based on the Condensation of Two Optically-Active Iridoids, C10-Synthons Obtained from Photo-Cycloadduct of Methyl 2,4-Dioxo-pentanoate-Isoprene, and Its App

One of the photocycloadducts obtained during methyl 2,4-dioxopentanoate to isoprene was converted to optically active iridoids.Using a CrCl2 reductive-couping reaction, proper combinations of two kinds of enantiomeric iridoids, 1-iriden-7-al and 9-benzylo

SYNTHESIS OF FUSICOCCA-2,8,10-TRIENE, A BIOGENETIC MISSING LINK, STARTING FROM STEREOSPECIFIC CONDENSATION OF TWO IRIDOID SYNTHONS

From two units of iridoid C10-synthons which could be prepared from one of the photoadducts of isoprene and methyl 2,4-dioxopentanoate, the hydrocarbon which can be designated as fusicocca-2,8-10-triene, a missing link in the biogenesis, was st