93242-25-2

Upstream product

• 100-68-5 methyl-phenyl-thioether 
• 590-86-3 isovaleraldehyde 
• 93242-21-8 4-methyl-1-(phenylthio)pentan-2-ol 
• 74-88-4 methyl iodide 

Downstream Products

• 82561-89-5 (Z)-7-Methyl-1-phenyl-4-phenylsulfanyl-oct-4-en-3-ol 
• 82561-91-9 (Z)-7-Methyl-4-phenylsulfanyl-oct-4-en-3-ol 
• 93242-34-3 C₁₂H₁₅LiS 
• 93242-11-6 (Z)-4-methyl-1-phenylsulfinyl-1-pentene 
• 82561-93-1 (Z)-2,8-Dimethyl-5-phenylsulfanyl-non-5-en-4-ol 
• 93242-13-8 (Z)-2-(phenylthio)-5-methyl-2-hexene 
• 93241-96-4 (E)-2-(phenylthio)-5-methyl-2-hexene 
• 93241-97-5 (E)-2-methyl-5-(phenylthio)-4-tridecene 
• 93242-47-8 7-methyl-1-phenyl-4-phenylthio-4-octen-3-ol 

Relevant academic research and scientific papers

Preparation and Reaction of 1-(Methylthio- and phenylthio)vinyllithium Reagents

An improved procedure for the preparation of 1-(methylthio- and phenylthio)vinyllithium reagents utilizing 2-methoxyalkyl sulfides was developed and their reactions with ketones, aldehydes, oxiranes, and alkyl halides were studied.

A CONVENIENT MATHOD FOR PREPARATION OF 1-(METHYLTHIO) AND 1-(PHENYLTHIO)VINYLLITHIUM REAGENTS

1-(Methylthio) and 1-(phenylthio)vinyllithiums were prepared by the treatment of the corresponding 2-methoxyethyl sulfides with twice molar amounts of butyllithium in the presence of N,N,N',N'-tetramethylethylenediamine (TMEDA). β-Alkylthio-β,γ-unsaturated alcohols were obtained in good yields by the reaction of the lithium salts with aldehydes.