93242-56-9Relevant academic research and scientific papers
Preparation and Reaction of 1-(Methylthio- and phenylthio)vinyllithium Reagents
Takeda, Takeshi,Furukawa, Hiroyuki,Fujimori, Mizue,Suzuki, Kouichi,Fujiwara, Tooru
, p. 1863 - 1869 (2007/10/02)
An improved procedure for the preparation of 1-(methylthio- and phenylthio)vinyllithium reagents utilizing 2-methoxyalkyl sulfides was developed and their reactions with ketones, aldehydes, oxiranes, and alkyl halides were studied.
A CONVENIENT MATHOD FOR PREPARATION OF 1-(METHYLTHIO) AND 1-(PHENYLTHIO)VINYLLITHIUM REAGENTS
Takeda, Takeshi,Furukawa, Hiroyuki,Fujiwara, Tooru
, p. 593 - 596 (2007/10/02)
1-(Methylthio) and 1-(phenylthio)vinyllithiums were prepared by the treatment of the corresponding 2-methoxyethyl sulfides with twice molar amounts of butyllithium in the presence of N,N,N',N'-tetramethylethylenediamine (TMEDA). β-Alkylthio-β,γ-unsaturated alcohols were obtained in good yields by the reaction of the lithium salts with aldehydes.
