93248-72-7

Upstream product

• 93248-68-1 6-Hydroxy-3-methyl-2-((E)-pent-3-enyl)-cyclohex-2-enone 
• 93248-69-2 (1R,2S)-4-Methyl-3-((E)-pent-3-enyl)-cyclohex-3-ene-1,2-diol 
• 87020-26-6 3-methyl-2-(pent-3-enyl)cyclohex-2-enone 
• 113526-16-2 1-methyl-2-(pent-2-enyl)-4-methoxycyclohex-1,4-diene 
• 113526-17-3 1-methyl-2-(pent-2-enyl)cyclohex-1-ene-4-one 
• 93248-71-6 (3aR,7aS)-6-Methyl-7-((E)-pent-3-enyl)-3a,4,5,7a-tetrahydro-benzo[1,3]dioxol-2-one 

Relevant academic research and scientific papers

Synthesis and Cyclisation of 4-Acetoxy-1-methyl-2-(pent-2-enyl)-cyclohexane-1,2-epoxide

4-Acetoxy-1-methyl-2-(pent-2-enyl)cyclohexane-1,2-epoxide(I) has been synthesised as follows: 3-(2-methyl-5-methoxyphenyl)propanol(IV) on treatment with pyridiniumchlorochromate in dichloromethane furnishes the aldehyde(V) which on normal Wittig condensat

1 -> 6 OXYGEN TRANSPOSITION OF A CYCLOHEX-2-ENONE

The 1 -> 6 transposition can be achieved by 6-hydroxylation, reduction to the cis-diol, cyclic carbonate formation, and reduction with sodium cyanoborohydride-tetrakis(triphenylphosphine)palladium(0)-tetrahydrofuran.