93253-37-3Relevant academic research and scientific papers
SYNTHESIS OF 1-ARYL-(GLYCOFURANO)IMIDAZOLIDINE-2-THIONES FROM NEW 2-(ALKYLAMINO)-2-DEOXYHEXOSES
Perez, Juan A. Galbis,Albarran, Juan C. Palacios,Requejo, Jose L. Jimenez,Gonzalez, Martin Avalos,Fernandez-Bolanos, Jose M.
, p. 131 - 142 (2007/10/02)
The new amino sugars 2-deoxy-2-(ethylamino)-α-L-glucopyranose, 2-deoxy-2-(propylamino)-α-L-glucopyranose, and 2-deoxy-2-(ethylamino)-α(or β)-L-mannopyranose have been prepared from L-arabinose by the aminonitrile synthesis.The reaction between these aminohexoses and aryl isothiocyanates affords the corresponding 3-alkyl-1-aryl-(1,2-dideoxy-α-L-glucofurano)imidazolidine-2-thiones and 3-alkyl-1-aryl-(1,2-dideoxy-β-L-mannofurano)imidazolidine-2-thiones.The structures of the new compounds described were elucidated by chemical and physical methods.
