932743-82-3Relevant articles and documents
Pd-catalyzed asymmetric allylic amination of Morita-Baylis-Hillman adduct derivatives using chiral diaminophosphine oxides: DIAPHOXs
Nemoto, Tetsuhiro,Fukuyama, Takashi,Yamamoto, Eri,Tamura, Shinji,Fukuda, Tomoaki,Matsumoto, Takayoshi,Akimoto, Yuichi,Hamada, Yasumasa
, p. 927 - 930 (2007/10/03)
(Chemical Equation Presented) Asymmetric allylic animation of allylic carbonates prepared from racemic Morita-Baylis-Hillman adducts proceeded in the presence of Pd catalyst, chiral diaminophosphine oxide (DIAPHOX), and BSA, affording the corresponding chiral aza-Morita-Baylis-Hillman adduct derivatives in excellent yield with up to 99% ee. The cyclic reaction products could be converted into various synthetically useful compounds such as chiral cyclic β-amino acids.
