93295-59-1Relevant articles and documents
METHODS FOR SYNTHESIS OF 1-METHYLOLALLENEPHOSPHONOUS ACID AND ITS HYDROXY ESTERS
Devedjiev, I.,Ganev, V.,Borisov, G.,Zabski, L.,Jedlinski, Z.
, p. 167 - 170 (2007/10/02)
From alkylene oxides and hypophosphorous acid 2-hydroxyesters of the hypophosphorus acid are formed.They undergo an exchange reaction with 2-butyne-1,4-diol as a result of which the corresponding glycol and 1-methylolallenephosphonous acid are obtained.The yield of the acid is quantitative.According to this method also 2-hydroxy esters of 1-methylolallenephosphonous acid are formed.Key words; Hypophosphorous acid esters with acetylenic alcohols; alkylene oxides; 2-hydroxy esters of 1 methylolallenephosphonous acid; allenephosphonous acid ; acetylene-allene rearrangement; 2-butine-1,4diol