93304-97-3

Basic information

• Product Name: Benzene, 1-[bis(phenylthio)methyl]-2-nitro-
• CAS NO: 93304-97-3
• Molecular Formula: C19H15NO2S2
• Molecular Weight: 353.466
• Mol File: 93304-97-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[bis(phenylthio)methyl]-2-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[bis(phenylthio)methyl]-2-nitro-(93304-97-3)
• EPA Substance Registry System: Benzene, 1-[bis(phenylthio)methyl]-2-nitro-(93304-97-3)

Safety Data

• Hazardous Substances Data: 93304-97-3(Hazardous Substances Data)

Upstream product

• 88-72-2 1-methyl-2-nitrobenzene 
• 882-33-7 diphenyldisulfane 
• 3561-67-9 bis(phenylthio)methane 
• 98-95-3 nitrobenzene 
• 108-98-5 thiophenol 
• 552-89-6 2-nitro-benzaldehyde 

Downstream Products

• 552-89-6 2-nitro-benzaldehyde 

Relevant articles and documents

Regioselective transition metal- and halogen-free direct dithiolation at C(sp3)-H of nitrotoluenes with diaryl disulfides

Here we describe a potassium tert-butoxide-mediated regioselective direct C-S bond formation at the C(sp3)-H position of nitrotoluenes with disulfides in DMSO at room temperature. The developed reaction generated, in good yields, various dithioacetals having OMe, halogen, and NH2 functionalities at various positions of the arene rings of the disulfides. Interestingly, in the absence of nitrotoluene, diaryl disulfides and diselenides underwent one-carbon homologation to form dithioacetals and diselenoacetals. Synthesized dithioacetals were transformed into 4-nitrobenzaldehyde and 7-(bis(phenylthio)methyl)-1H-indole.

Mass spectral studies on some nitrobenzylidene thioacetal derivatives

The electron impact mass spectral studies on some nitrobenzylidene thioacetal derivatives showed two different mechanisms of oxygen transfer from the nitro group to the sulfur containing fragments via intra-and inter-oxygen transfer. The two mechanisms ar

Vicarious Substitution of Hydrogen with Carbanions of Dithioacetals of Aldehydes

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