93399-99-6

Basic information

• Product Name: 3-Hexen-2-ol, 5-methyl-, (E)-
• CAS NO: 93399-99-6
• Molecular Formula: C7H14O
• Molecular Weight: 114.188
• Mol File: 93399-99-6.mol

Chemical Properties

• CAS DataBase Reference: 3-Hexen-2-ol, 5-methyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Hexen-2-ol, 5-methyl-, (E)-(93399-99-6)
• EPA Substance Registry System: 3-Hexen-2-ol, 5-methyl-, (E)-(93399-99-6)

Safety Data

• Hazardous Substances Data: 93399-99-6(Hazardous Substances Data)

Upstream product

• 5166-53-0 5-methyl-3-hexene-2-one 

Downstream Products

• 847459-47-6 benzoic acid (2S,3E)-5-methylhex-3-en-2-yl ester 
• 847459-46-5 (2S,3E)-5-methylhex-3-en-2-ol 
• 847459-48-7 benzoic acid (2R,3E)-5-methylhex-3-en-2-yl ester 
• 1669-43-8 (E)-4-isopropylbut-3-en-2-one 
• 110-12-3 5-Methyl-2-hexanone 
• 80277-63-0 E-5-methyl-3-hexen-2-yl p-nitrobenzoate 
• 97946-17-3 (E)-5-methylhex-3-en-2-yl N-phenylcarbamate 

Relevant articles and documents

Lanthanide replacement in organic synthesis: Luche-type reduction of α,β-unsaturated ketones in the presence of calcium triflate

Development of a calcium-mediated regioselective 1,2-reduction of challenging α,β-unsaturated ketones, such as 2-cyclopententone, is reported. The corresponding allylic alcohols are obtained in very good regioselectivities using Ca(OTf)2 and NaBH4. Furthermore, we have shown that our method can stereoselectively reduce aziridinyl ketones.