934020-65-2Relevant academic research and scientific papers
The Pauson-Khand reaction as a new entry to the synthesis of bridged bicyclic heterocycles: application to the enantioselective total?synthesis of (-)-alstonerine
Miller, Kenneth A.,Shanahan, Charles S.,Martin, Stephen F.
, p. 6884 - 6900 (2008/09/21)
The first application of the Pauson-Khand reaction (PKR) to the synthesis of azabridged bicyclic structures is described. Compounds containing azabicyclo[3.3.1]nonane and azabicyclo[3.2.1]octane rings fused to cyclopentenones were efficiently constructed
Concise, enantioselective total synthesis of (-)-alstonerine
Miller, Kenneth A.,Martin, Stephen F.
, p. 1113 - 1116 (2007/10/03)
(Chemical Equation Presented) A novel enantioselective total synthesis of (-)-alstonerine has been completed that requires only 15 steps from L-tryptophan. The synthesis features the first application of a Pauson-Khand reaction to synthesize an azabridged
