93403-93-1Relevant academic research and scientific papers
Photoreactions of Halogeno-1,4-naphthoquinones with Electron-rich Alkenes
Maruyama, Kazuhiro,Imahori, Hiroshi
, p. 257 - 265 (2007/10/02)
Photochemical reactions of 2,3-dichloro-1,4-naphthoquinone with 1,1-diarylethylenes or the related electron-rich alkenes have been investigated by steady-state photoreactions, flash photolysis, and kinetic analyses based on the Stern-Volmer experiment and concentration dependence of quantum yields; there is reasonable agreement between them.In acetonitrile a radical ion pair composed of a quinone radical anion and a 1,1-diarylethylene radical cation was observed, while no intermediate was observed in benzene.Dimerization products derived from radical cations were obtained only in the photoreaction of quinone with 1,1-bis(4-methoxyphenyl)ethylene.
Photoinduced Electron-Transfer-Initiated Aromatic Cyclization
Maruyama, Kazuhiro,Otsuki, Tetsuo,Tai, Seiji
, p. 52 - 60 (2007/10/02)
Photochemical reaction of substituted 1,4-naphthoquinones with 1,1-diarylethylenes led primarily to benzanthracene-7,12-dione derivatives.Evidence was obtained that the photoreaction proceeded via a photoinduced electron-transfer process.Extension of t
