934201-65-7Relevant academic research and scientific papers
HIGH-VALENT PALLADIUM FLUORIDE COMPLEXES AND USES THEREOF
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, (2012/03/11)
The present invention provides novel high-valent palladium complexes. The complexes typically include multi-dentate ligands that stabilize the octahedral coordination sphere of the palladium(IV) atom. These complexes are useful in fluorinating organic compounds and preparing high-valent palladium fluoride complexes. The invention is particularly useful for fluorinating compounds with 19F for PET imaging.
Carbon-nitrogen bond-forming reactions of palladacycles with hypervalent iodine reagents
Dick, Allison R.,Remy, Matthew S.,Kampf, Jeff W.,Sanford, Melanie S.
, p. 1365 - 1370 (2008/10/09)
Palladium(II) complexes containing bidentate cyclometalated C-N chelating ligands are shown to react with PhI=NTs at room temperature to insert "NTs" into the Pd-C bond. This "NTs" insertion reaction has been applied to palladacyclic complexes of azobenze
