934219-97-3

Upstream product

• 934219-96-2 (R)-4-benzyl-3-{(S)-2-[(R)-(3,4-dimethoxyphenyl)(triisopropylsilyloxy)methyl]-5-hexenoyl}-2-oxazolidinone 
• 1577-22-6 5-hexenoic acid 
• 120-14-9 3,4-dimethoxy-benzaldehyde 
• 934219-95-1 (R)-4-benzyl-3-{(S)-2-[(R)-(hydroxy)(3,4-dimethoxyphenyl)methyl]-5-hexenoyl}-2-oxazolidinone 
• 344597-00-8 (R)-4-benzyl-3-(hex-5′-enoyl)oxazolidin-2-one 

Downstream Products

• 934219-98-4 (5R,6R)-6-(3,4-dimethoxyphenyl)-6-(triisopropylsilyloxy)-5-trityloxymethyl-1-hexene 
• 934219-99-5 (4R,5R)-5-(3,4-dimethoxyphenyl)-5-(triisopropylsilyloxy)-4-(trityloxymethyl)pentanoic acid 
• 934220-01-6 (S)-4-benzyl-3-[(4R,5R)-5-(3,4-dimethoxyphenyl)-5-(triisopropylsilyloxy)-4-(trityloxymethyl)pentanoyl]-2-oxazolidinone 
• 934220-00-5 (R)-4-benzyl-3-[(4R,5R)-5-(3,4-dimethoxyphenyl)-5-(triisopropylsilyloxy)-4-(trityloxymethyl)pentanoyl]-2-oxazolidinone 
• 934220-03-8 (S)-4-benzyl-3-{(S)-2-[(2R,3R)-3-(3,4-dimethoxyphenyl)-3-(triisopropylsilyloxy)-2-(trityloxymethyl)prop-1-yl]-4-pentenoyl}-2-oxazolidinone 
• 934220-02-7 (R)-4-benzyl-3-{(R)-2-[(2R,3R)-3-(3,4-dimethoxyphenyl)-3-(triisopropylsilyloxy)-2-(trityloxymethyl)prop-1-yl]-4-pentenoyl}-2-oxazolidinone 
• 934220-05-0 (S)-2-[(2R,3R)-3-(3,4-dimethoxyphenyl)-3-(triisopropylsilyloxy)-2-(trityloxymethyl)prop-1-yl]-4-penten-1-ol 
• 934220-04-9 (R)-2-[(2R,3R)-3-(3,4-dimethoxyphenyl)-3-(triisopropylsilyloxy)-2-(trityloxymethyl)prop-1-yl]-4-penten-1-ol 
• 934220-06-1 (R)-2-[(2R,3R)-3-(3,4-dimethoxyphenyl)-3-(triisopropylsilyloxy)-2-(trityloxymethyl)prop-1-yl]-4-pentenal 
• 934220-07-2 (S)-2-[(2R,3R)-3-(3,4-dimethoxyphenyl)-3-(triisopropylsilyloxy)-2-(trityloxymethyl)prop-1-yl]-4-pentenal 
• 934220-09-4 (1R,2R,4R)-2-allyl-5-hydroxy-1-(3,4-dimethoxyphenyl)-4-[(S)-(3,4-dimethoxyphenyl)(triisopropylsilyloxy)methyl]pentyl acetate 
• 934220-13-0 (2R,3R,5R)-2-(3,4-dimethoxyphenyl)-5-[(R)-(3,4-dimethoxyphenyl)(triisopropylsilyloxy)methyl]-3-(2-propen-1-yl)tetrahydropyran 
• 934220-15-2 (2R,3R,5R)-3-(3,4-dimethoxycinnamyl)-2-(3,4-dimethoxyphenyl)-5-[(R)-(3,4-dimethoxyphenyl)(triisopropylsilyloxy)methyl]tetrahydropyran 
• 934220-11-8 (1S,2S)-1-(3,4-dimethoxyphenyl)-2-[(2R,3R)-3-(3,4-dimethoxyphenyl)-3-(triisopropylsilyloxy)-2-(trityloxymethyl)prop-1-yl]-4-penten-1-ol 

Relevant academic research and scientific papers

Determination of the stereochemistry of the tetrahydropyran sesquineolignans morinols A and B

The 7′,8′-stereochemistry of the tetrahydropyran sesquineolignans morinols A and B was determined as threo via synthetic studies and by comparison of NMR data of 7′,8′-threo-morinol and 7′,8′-erythro-morinol. This study also confirmed that the biosynthetic process produces enantiomeric mixtures of morinols A and B. This was ascertained by comparing the specific rotations of synthesized morinols A and B with those of naturally occurring morinols A and B.