934243-02-4

Basic information

• Product Name: (-)-(3S,1E)-[tert-butyl(dimethyl)(3-phenyl-but-1-enyl)]silane
• Synonyms: (-)-(3S,1E)-[tert-butyl(dimethyl)(3-phenyl-but-1-enyl)]silane
• CAS NO: 934243-02-4
• Molecular Weight: 246.468
• Mol File: 934243-02-4.mol

Chemical Properties

• CAS DataBase Reference: (-)-(3S,1E)-[tert-butyl(dimethyl)(3-phenyl-but-1-enyl)]silane(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(3S,1E)-[tert-butyl(dimethyl)(3-phenyl-but-1-enyl)]silane(934243-02-4)
• EPA Substance Registry System: (-)-(3S,1E)-[tert-butyl(dimethyl)(3-phenyl-but-1-enyl)]silane(934243-02-4)

Safety Data

• Hazardous Substances Data: 934243-02-4(Hazardous Substances Data)

Upstream product

• 301664-44-8 1-[tert-butyl(dimethyl)silanyl]but-2-yn-1-ol 
• 80594-40-7 1-[tert-butyl(dimethyl)silanyl]but-2-yn-1-one 
• 934242-93-0 (-)-(1R,2Z)-1-[tert-butyl(dimethyl)silanyl]-but-2-enyl pentafluorobenzoate 
• 1078-58-6 diphenylzinc 

Downstream Products

• 7782-26-5 (R)-2-Phenylpropionic acid 

Relevant articles and documents

Highly diastereoselective preparation of (E)-alkenylsilanes bearing an α-chiral center

(Chemical Equation Presented) The copper(I)-mediated anti-S N2′ allylic substitution allows a highly stereoselective preparation of alkenylsilanes bearing a chiral center in the α-position with high transfer of chirality. These alkenylsilanes were converted into α,β-unsaturated ketones or into the corresponding boronic esters without loss of the chiral information.