93426-68-7

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 68378-82-5 1-(6-methyl-3,4-dihydro-2H-pyran-2-yl)-propan-1-ol 
• 68378-82-5 1-(6-Methyl-3,4-dihydro-2H-pyran-2-yl)-propan-1-ol 
• 100-73-2 acrolein dimer 
• 110595-74-9 4-ethyl-2,2-dimethyl-5-(4-oxo-3-phenylselenopentyl)-1,3-dioxolane 
• 104555-42-2 (4S,5S)-4-ethyl-2,2-dimethyl-5-(4-pentenyl)-1,3-dioxolane 
• 110659-30-8 (4'S,5'S)-5-(5-Ethyl-2,2-dimethyldioxolan-4-yl)pentan-2-one 
• 90113-08-9 1-(3,4-Dihydro-2H-pyran-2-yl)-propan-1-ol 

Downstream Products

• 88525-42-2 exo-3,4-dehydrobrevicomin 
• 62255-25-8 exo-7-ethyl-5-methyl-6,8-dioxabicyclo<3.2.1>oct-3-ene 

Relevant academic research and scientific papers

SYNTHESIS OF BOTH THE ENANTIOMERS OF 7-ETHYL-5-METHYL-6,8-DIOXABICYCLOOCT-3-ENE, THE MUS MUSCULUS (HOUSE MOUSE) PHEROMONE

Both the enantiomers of the pheromone of the male mouse Mus musculus, exo-7-ethyl-5-methyl-6,8-dioxabicyclooct-3-ene, were synthesized from the enantiomers of tartaric acid.

REMARKABLE STEREOCONTROL IN THE ADDITION OF AN ANION TO AN α-ALKOXYALDEHYDE BY ENCOURAGING OR DISCOURAGING INTERNAL COMPLEXATION. APPLICATION TO BRIEF SYNTHESES OF THE MUS MUSCULUS (HOUSE MOUSE) PHEROMONE AND EXO-BREVICOMIN.

Stereoselective addition of ethylmetallic reagents to acrolein dimer 1 and the conversion of the threo alcohol 4t to exo-brevicomin and the Mus musculus pheromone are reported.