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Synthesis of the β-1,3-glucan, laminarahexaose: NMR and conformational studies
Mo, Kai-For,Li, Huiqing,Mague, Joel T.,Ensley, Harry E.
experimental part, p. 439 - 447 (2009/05/27)
The synthesis of laminarahexaose is described. NMR studies of several of the intermediates leading to the β-1,3-glucan show anomalously small coupling constants for some of the C-1 hydrogens. An X-ray structure for the protected hexasaccharide shows that
