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2-Dicyclohexylphosphino-2μ,4μ,6μ-triisopropylbiphenyl gold(I) bis(trifluoromethanesulfonyl)imide is a gold-based organocatalyst with a unique structure that features a dicyclohexylphosphino group, a triisopropylbiphenyl moiety, and bis(trifluoromethanesulfonyl)imide ligands. This complex has gained significant attention in the field of catalysis due to its ability to facilitate various chemical reactions with high efficiency and selectivity.

934506-10-2

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934506-10-2 Usage

Uses

Used in Chemical Catalysis:
2-Dicyclohexylphosphino-2μ,4μ,6μ-triisopropylbiphenyl gold(I) bis(trifluoromethanesulfonyl)imide is used as a catalyst for a variety of chemical reactions, including isomerization of allenyl carbinol esters, hydroxyand methoxycyclization, and cycloisomerisation of diynes. Its unique structure and electronic properties enable it to promote these reactions with high efficiency and selectivity, making it a valuable tool in the synthesis of complex organic molecules.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, 2-Dicyclohexylphosphino-2μ,4μ,6μ-triisopropylbiphenyl gold(I) bis(trifluoromethanesulfonyl)imide is used as a catalyst for the synthesis of pharmaceutical compounds. Its ability to facilitate challenging chemical transformations with high efficiency and selectivity makes it a valuable asset in the development of new drugs and the improvement of existing ones.
Used in Materials Science:
2-Dicyclohexylphosphino-2μ,4μ,6μ-triisopropylbiphenyl gold(I) bis(trifluoromethanesulfonyl)imide is also used in materials science for the synthesis of advanced materials with unique properties. Its catalytic activity can be employed to create new polymers, nanoparticles, and other materials with potential applications in various fields, such as electronics, energy storage, and environmental remediation.
Overall, 2-Dicyclohexylphosphino-2μ,4μ,6μ-triisopropylbiphenyl gold(I) bis(trifluoromethanesulfonyl)imide is a versatile and powerful catalyst with a wide range of applications in various industries, including chemical synthesis, pharmaceuticals, and materials science. Its unique structure and properties make it a valuable tool for researchers and scientists working on the development of new and improved chemical processes and products.

Check Digit Verification of cas no

The CAS Registry Mumber 934506-10-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 9,3,4,5,0 and 6 respectively; the second part has 2 digits, 1 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 934506-10:
(8*9)+(7*3)+(6*4)+(5*5)+(4*0)+(3*6)+(2*1)+(1*0)=162
162 % 10 = 2
So 934506-10-2 is a valid CAS Registry Number.

934506-10-2 Well-known Company Product Price

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  • Aldrich

  • (691674)  2-Dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenylgold(I)bis(trifluoromethanesulfonyl)imide  

  • 934506-10-2

  • 691674-250MG

  • 1,668.42CNY

  • Detail
  • Aldrich

  • (691674)  2-Dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenylgold(I)bis(trifluoromethanesulfonyl)imide  

  • 934506-10-2

  • 691674-1G

  • 5,281.38CNY

  • Detail

934506-10-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name bis(trifluoromethylsulfonyl)azanide,dicyclohexyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane,gold(1+)

1.2 Other means of identification

Product number -
Other names tBuXPhosAuNTf

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:934506-10-2 SDS

934506-10-2Downstream Products

934506-10-2Relevant academic research and scientific papers

A Gold Carbene Manifold to Prepare Fused γ-Lactams by Oxidative Cyclisation of Ynamides

Sánchez-Cantalejo, Fernando,Priest, Joshua D.,Davies, Paul W.

supporting information, p. 17215 - 17219 (2018/11/10)

Gold-catalysed oxidative cyclisation reactions of ynamides offer great promise in γ-lactam synthesis but are limited by preferential over-oxidation to form α-keto imides. Evaluating the factors that might limit N-cyclisation pathways led to effective gold-catalysed conditions that allow access to different fused γ-lactams on changing the ynamide N-substituent and accommodate previously incompatible substitution patterns. New and efficient methods for the synthesis of functionalised 3-aryl indoles and cyclohepta[c]pyrrol-1-one derivatives are presented. These conditions illustrate the complementarity of gold catalysis to other metals.

Construction of eight-membered carbocycles through gold catalysis with acetylene-tethered silyl enol ethers

Iwai, Tomohiro,Okochi, Hiori,Ito, Hideto,Sawamura, Masaya

supporting information, p. 4239 - 4242 (2013/05/08)

Semihollow triethynylphosphanes were synthesized and employed as ligands in the gold-catalyzed 8-exo-dig cyclization of acetylene-tethered silyl enol ethers to obtain eight-membered-ring carbocycles (see scheme). The gold-phosphane catalysts promoted eith

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