93453-17-9Relevant articles and documents
Vinylsulfone-modified carbohydrates: First general route to D-lividosamine (2-amino-2,3-dideoxy-D-glucose) and its new analogues
Ravindran, Bindu,Deshpande, Sachin G,Pathak, Tanmaya
, p. 1093 - 1098 (2007/10/03)
A general route to D-lividosamine and its new analogues has been devised for the first time. The essence of the present synthetic route lies in the diastereoselective introduction of N-monoalkylated and N-dialkylated amines to C-2 carbons of methyl 2,3-di
Further Aspects of the Reduction of Dithiocarbonates with Tributyltin Hydride and Deuteride
Conway, Richard J.,Nagel, Jennifer P.,Stick, Robert V.,Tilbrook, D. Matthew G.
, p. 939 - 945 (2007/10/02)
The reduction of 1,2:5,6-di-O-isopropylidene-3-O-(methylthio)thiocarbonyl-β-D-idose, -talose, and -(3-(2H))talose with tributyltin hydride and deuteride leads to the deoxy sugar and some deuteriumcontaining deoxy sugars.A modification of the normal procedure allows for reduction with tributyltin hydride generated in situ.As well, the reduction of some dithiocarbonates derived from glycosides of N-acetyl-D-glucosamine allows to a variety of dideoxy and trideoxy sugars.