93453-17-9

Upstream product

• 100638-83-3 methyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-O--α-D-glucopyranoside 
• 6619-02-9 methyl N-acetyl-2-amino-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 330825-80-4 methyl 2-N-benzylamino-2,3-dideoxy-4,6-O-(phenylmethylene)-α-D-ribo-hexopyranoside 
• 293294-12-9 methyl 2-N-benzylamino-2,3-dideoxy-4,6-O-(phenylmethylene)-3-C-phenylsulfonyl-α-D-glucopyranoside 
• 273921-07-6 methyl 2,3-dideoxy-4,6-O-(phenylmethylene)-3-C-phenylsulfonyl-α-D-erythro-hex-2-enopyranoside 
• 108-24-7 acetic anhydride 

Relevant academic research and scientific papers

Vinylsulfone-modified carbohydrates: First general route to D-lividosamine (2-amino-2,3-dideoxy-D-glucose) and its new analogues

A general route to D-lividosamine and its new analogues has been devised for the first time. The essence of the present synthetic route lies in the diastereoselective introduction of N-monoalkylated and N-dialkylated amines to C-2 carbons of methyl 2,3-di

Further Aspects of the Reduction of Dithiocarbonates with Tributyltin Hydride and Deuteride

The reduction of 1,2:5,6-di-O-isopropylidene-3-O-(methylthio)thiocarbonyl-β-D-idose, -talose, and -(3-(2H))talose with tributyltin hydride and deuteride leads to the deoxy sugar and some deuteriumcontaining deoxy sugars.A modification of the normal procedure allows for reduction with tributyltin hydride generated in situ.As well, the reduction of some dithiocarbonates derived from glycosides of N-acetyl-D-glucosamine allows to a variety of dideoxy and trideoxy sugars.