934545-49-0

Basic information

• Product Name: (S)-2-((4-methoxybenzyl)oxy)hex-5-en-1-ol
• Synonyms: (S)-2-((4-methoxybenzyl)oxy)hex-5-en-1-ol
• CAS NO: 934545-49-0
• Molecular Weight: 236.311
• Mol File: 934545-49-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-2-((4-methoxybenzyl)oxy)hex-5-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-((4-methoxybenzyl)oxy)hex-5-en-1-ol(934545-49-0)
• EPA Substance Registry System: (S)-2-((4-methoxybenzyl)oxy)hex-5-en-1-ol(934545-49-0)

Safety Data

• Hazardous Substances Data: 934545-49-0(Hazardous Substances Data)

Upstream product

• 934545-47-8 C₁₄H₁₈O₃ 
• 334972-54-2 (S)-tert-butyl((2-((4-methoxybenzyl)oxy)hex-5-en-1-yl)oxy)dimethylsilane 
• 334972-53-1 (S)-1-((tert-butyldimethylsilyl)oxy)hex-5-en-2-ol 
• 764-59-0 hex-5-en-1-al 
• 127102-61-8 (S)-hex-5-ene-1,2-diol 
• 10353-53-4 1,2-epoxy-5-hexene 

Downstream Products

• 442913-72-6 (S)-2-((4-methoxybenzyl)oxy)hex-5-enoic acid 
• 934545-55-8 C₂₃H₃₂O₆ 
• 934545-53-6 C₂₅H₃₆O₆ 

Relevant articles and documents

Formal synthesis of pinolide via l-proline-catalyzed sequential α-aminooxylation, Horner-Wadsworth-Emmons olefination and Sharpless asymmetric dihydroxylation

A convergent, formal enantioselective synthesis of pinolide, a new nonenolide, has been achieved with high enantiomeric purity (99% ee) starting from readily available raw materials. The main highlight of the synthetic strategy is the application of l-proline catalyzed sequential α-aminooxylation and Horner-Wadsworth-Emmons olefination of an aldehyde, Sharpless asymmetric dihydroxylation and Steglich esterification as the key steps for the construction of a key chiral intermediate of the target molecule.