934587-87-8

Upstream product

• 17042-40-9 4-methoxyphenyl 2,3,4,6-tetra-O-acetyl-1-α-D-mannopyranoside 
• 83-87-4 D-Mannose pentaacetate 
• 530-26-7 D-Mannose 
• 28541-75-5 p-methoxyphenyl α-D-mannopyranoside 
• 934587-86-7 2-iodomethyl-6-(4-methoxy-phenoxy)-tetrahydro-pyran-3,4,5-triol 
• 150-76-5 4-methoxy-phenol 

Downstream Products

• 934587-99-2 4-methoxyphenyl 3-O-benzyl-α-D-rhamnopyranoside 
• 934588-01-9 C₃₀H₃₀O₈ 
• 934587-88-9 2,3-dimethoxy-7-(4-methoxy-phenoxy)-2,3,5-trimethyl-hexahydro-pyrano[3,4-b][1,4]dioxin-8-ol 
• 934587-95-8 4-(4-methoxy-phenoxy)-2,2,6-trimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol 
• 1304123-39-4 4-methoxyphenyl 2,4-di-O-acetyl-α-D-rhamnopyranoside 
• 1304123-41-8 4-methoxyphenyl 2,4-di-O-acetyl-3-O-trifluoromethanesulfonyl-α-D-rhamnopyranoside 
• 1304123-43-0 4-methoxyphenyl 2,3,4-tri-O-acetyl-6-deoxy-α-D-altopyranoside 
• 1304123-37-2 4-methoxyphenyl 2,4-di-O-acetyl-3-O-benzyl-α-D-rhamnopyranoside 
• 934587-91-4 C₃₂H₃₂O₁₀ 
• 934588-00-8 C₃₄H₃₂O₈ 
• 934587-89-0 4-oxo-pentanoic acid 2,3-dimethoxy-7-(4-methoxy-phenoxy)-2,3,5-trimethyl-hexahydro-pyrano[3,4-b][1,4]dioxin-8-yl ester 
• 934588-03-1 C₂₇H₂₆O₈ 
• 934587-92-5 4-oxo-pentanoic acid 4,5-diacetoxy-2-(4-methoxy-phenoxy)-6-methyl-tetrahydro-pyran-3-yl ester 
• 934587-96-9 7-benzyloxy-4-(4-methoxy-phenoxy)-2,2,6-trimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran 

Relevant academic research and scientific papers

Serendipitous one-pot synthesis of chiral dienes from pyranosidic 2,4-bistriflates

Attempted nucleophilic displacements of L-rhamnosyl 2,4-bistriflates led to serendipitous formation of a chiral diene via competing cascade eliminations. The reaction also followed the same pathway with D-rhamnosyl and D-mannosyl 2,4-bistriflates substrat

Bronsted acid-promoted glycosylations of disaccharide glycal substructures of the saccharomicins

An acid-promoted glycosylate and alkynol cycloisomerization sequence provided direct access to the 2-deoxytrisaccharide corresponding to the fucose-saccharosamine-digitoxose substructure of saccharomicin B. In the course of this work, the absolute stereochemistry of the repeating fucose- saccharosamine disaccharide of saccharomicins was also confirmed.

Practical synthesis of valuable d-rhamnoside building blocks for oligosaccharide synthesis

The efficient synthesis of d-rhamnoside and the corresponding methods for its regioselective protections and deprotections have been developed in order to provide key building blocks for complex oligosaccharide syntheses toward vaccines against bacterial infections.