934601-94-2Relevant academic research and scientific papers
Preparation of strained axially chiral (1,5)naphthalenophanes by photo-dehydro-diels-Alder reaction
Wessig, Pablo,Matthes, Annika
, p. 2642 - 2650 (2011/04/23)
The preparation of 10 (1,5)naphthalenophanes (10a-j) by photo-dehydro-Diels-Alder (PDDA) reaction is described. Owing to hindered rotation around the biaryl axis, compounds 10 are axially chiral and the separation of enantiomers by chiral HPLC was demonst
The Photo-Dehydro-Diels-Alder (PDDA) reaction - A powerful method for the preparation of biaryls
Wessig, Pablo,Mueller, Gunnar,Pick, Charlotte,Matthes, Annika
, p. 464 - 477 (2007/12/27)
The photochemically initiated dehydro-Diels-Alder (PDDA) reaction is an efficient and versatile method for the preparation of biaryls. The ring closure may take place both inter- and intramolecularly, of which the intramolecular variant is more productive
