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[Cu(6,6'-bis(4-phenylthiazol-2-yl)-2,2'-bipyridine)(ClO4)2]*(nitromethane) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 934713-98-1 Structure
  • Basic information

    1. Product Name: [Cu(6,6'-bis(4-phenylthiazol-2-yl)-2,2'-bipyridine)(ClO4)2]*(nitromethane)
    2. Synonyms:
    3. CAS NO:934713-98-1
    4. Molecular Formula:
    5. Molecular Weight: 798.097
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 934713-98-1.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [Cu(6,6'-bis(4-phenylthiazol-2-yl)-2,2'-bipyridine)(ClO4)2]*(nitromethane)(CAS DataBase Reference)
    10. NIST Chemistry Reference: [Cu(6,6'-bis(4-phenylthiazol-2-yl)-2,2'-bipyridine)(ClO4)2]*(nitromethane)(934713-98-1)
    11. EPA Substance Registry System: [Cu(6,6'-bis(4-phenylthiazol-2-yl)-2,2'-bipyridine)(ClO4)2]*(nitromethane)(934713-98-1)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 934713-98-1(Hazardous Substances Data)

934713-98-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 934713-98-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 9,3,4,7,1 and 3 respectively; the second part has 2 digits, 9 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 934713-98:
(8*9)+(7*3)+(6*4)+(5*7)+(4*1)+(3*3)+(2*9)+(1*8)=191
191 % 10 = 1
So 934713-98-1 is a valid CAS Registry Number.

934713-98-1Downstream Products

934713-98-1Relevant articles and documents

Localization and delocalization in a mixed-valence dicopper helicate

Jeffery, John C.,Riis-Johannessen, Thomas,Anderson, Callum J.,Adams, Christopher J.,Robinson, Adam,Argent, Stephen P.,Ward, Michael D.,Rice, Craig R.

, p. 2417 - 2426 (2007)

The coordination chemistry of the tetradentate pyridyl-thiazole (py-tz) N-donor ligand 6,6′-bis(4-phenylthiazol-2-yl)-2,2′-bipyridine (L1) has been investigated. Reaction of L1 with equimolar copper(II) ions results in the formation of the single-stranded mononuclear complex [Cu(L1)(ClO4)2] (1), whereas reaction with copper(I) ions results in the double-stranded dinuclear helicate [Cu 2(L1)2][PF6]2 (2). Both complexes were characterized by X-ray crystallography, UV-vis spectroscopy, and electrospray ionization mass spectroscopy (as well as 1H NMR spectroscopy for diamagnetic 2). Complex 2 is redox-active and, upon one-electron oxidation, forms the stable tricationic mixed-valence helicate [Cu2(L1)2]3+ (3). This species can also be prepared in situ by combining [Cu(MeCN)4][BF4], [Cu-(H2O)6][BF4]2, and L1 in a 1:1:2 ratio in nitromethane. X-ray crystallographic analysis of 3 provides structural evidence for the presence of an internuclear Cu-Cu bond, with an even distribution of spin density across the two Cu centers. Room-temperature UV-vis spectroscopy is consistent with this finding; however, frozen-glass EPR spectroscopic investigations suggest solvatochromic behavior at 110 K, with the [Cu2]3+ core varying from localized to delocalized depending on the solvent polarity.

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