93472-34-5Relevant academic research and scientific papers
Synthesis and Carbodemetalation Reactions of 4-Methyl- and 5-Aryl-2-(trimethylsilyl)oxazoles. C-C Bond Formation at C2 of the Oxazole Ring
Dondoni, Alessandro,Fantin, Giancarlo,Fogagnolo, Marco,Medici, Alessandro,Pedrini, Paola
, p. 3413 - 3420 (2007/10/02)
The title compounds 6a-d have been prepared by sequential lithiation and silylation of the corresponding 2-H oxazoles and isomerization of the resulting α-isocyano silyl enol ethers.Silyloxazoles 6a-d behave as stable 2-oxazolyl anion equivalents toward v
ADDITION OF 2-SILYLAZOLES TO HETEROARYL CATIONS. SYNTHESIS OF UNSYMMETRICAL AZADIARYLS
Dondoni, Alessandro,Dall'Occo, Tiziano,Galliani, Guido,Mastellari, Annarosa,Medici, Alessandro
, p. 3637 - 3640 (2007/10/02)
Thiazole, pyridine and some of their benzoderivatives react via their N-ethoxycarbonyl chlorides with 2-trimethylsilylthiazole (1a) and 4-methyl-2-trimethylsilyloxazole (1b) to give the corresponding adducts at Cα which by oxidative deacylation afford azadiaryls.
