934843-35-3Relevant academic research and scientific papers
Charge distribution in cationic molybdenum imido alkylidene N?heterocyclic carbene complexes: A combined X?ray, XaS, XeS, DFT, M?ssbauer, and catalysis approach
Benedikter, Mathis,Musso, Janis,Kesharwani, Manoj K.,Leonard Sterz,Elser, Iris,Ziegler, Felix,Fischer, Felix,Plietker, Bernd,Frey, Wolfgang,Kastner, Johannes,Winkler, Mario,van Slageren, Joris,Nowakowski, Michal,Bauer, Matthias,Buchmeiser, Michael R.
, p. 14810 - 14823 (2020)
The charge delocalization between the N-heterocyclic carbene (NHC) and the metal in cationic molybdenum imido alkylidene NHC mono(nonafluoro-tert-butoxide) complexes has been studied for different NHCs, i.e., 1,3-dimesitylimidazol-2-ylidene (IMes), 1,3-di
PROCESS FOR PRODUCING ORGANIC TRANSITION METAL COMPLEX COMPOUND, METATHESIS CATALYST PRODUCED BY THE PROCESS, METATHESIS POLYMER FORMED BY RING OPENING POLYMERIZATION WITH THE SAME, AND PROCESS FOR PRODUCING POLYMER WITH THE SAME
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Page/Page column 22, (2008/12/07)
A process for synthesizing an organic transition metal complex compound with an atom group having an electron-donor ability, in an industrially and economically advantageous manner, without a compound having a proton-donor ability being a metal salt, and a metathesis catalyst produced with the use of the above process, are provided. A process for producing an organic transition metal complex compound in which an atom group having an electron-withdrawing ability can be converted into an atom group having a stronger electron-donor ability, by contacting an compound having a proton-donor ability with the organic transition metal complex compound with an atom group having an electron-withdrawing ability, in the presence of an basic compound, and a metathesis catalyst of which the content of an alkali metal is reduced, and which is obtainable with the use of the above process, are provided.
