935457-58-2

Upstream product

• 2622-05-1 allylmagnesium bromide 
• 132969-60-9 (2S)-3-[(4-methoxybenzyl)oxy]-2-methylpropanal 
• 24850-33-7 allyltributylstanane 
• 132969-71-2 methyl (2S)-[(4-methoxybenzyl)oxy]-2-methylpropanoate 
• 105-13-5 4-Methoxybenzyl alcohol 

Downstream Products

• 1228675-61-3 (2S,3R,E)-11-((tert-butyldimethylsilyl)oxy)-1-((4-methoxybenzyl)oxy)-2-methyl-7-((trimethylsilyl)methylene)undecan-3-ol 
• 874914-31-5 (2S,3R)-3-hydroxy-2-methylhex-5-enyl 4-methylbenzenesulfonate 
• 935457-52-6 (5S,6S)-((2S,3R)-2-methyl-1-(tosyloxy)hex-5-en-3-yl)-6,8-dimethyl-5-(triethylsilyloxy)non-8-enoate 
• 1338070-51-1 (5S,6R)-6-(3-benzyloxypropyl)-2-[3-(tert-butyldiphenylsilyloxy)propyl]-5-methyl-5,6-dihydro-4H-pyran-4-one 
• 1315277-80-5 (5R,6R)-6-(3-benzyloxypropyl)-2-[3-(tert-butyldiphenylsilyloxy)propyl]-5-methyl-5,6-dihydro-4H-pyran-4-one 
• 1315278-19-3 (2R,3R)-6-benzyloxy-3-(4-methoxybenzyloxy)-2-methyl-1-hexanoic acid 
• 1315278-18-2 C₂₂H₂₈O₄ 
• 1315278-17-1 (2S,3R)-6-benzyloxy-3-(4-methoxybenzyloxy)-2-methyl-1-hexanol 
• 1315278-16-0 C₂₂H₂₈O₄ 
• 1315278-15-9 C₁₅H₂₂O₄ 
• 1315278-14-8 C₁₅H₂₀O₃ 
• 1315277-72-5 C₂₉H₃₄O₄S 

Relevant academic research and scientific papers

A ring-closing metathesis (RCM)-based approach to mycolactonesa A/B

The total synthesis of the mycobacterial toxins mycolactones A/B (1 a/b) has been accomplished based on a strategy built around the construction of the mycolactone core through ring-closing metathesis. By employing the Grubbs second-generation catalyst, t

Total synthesis and evaluation of phostriecin and key structural analogues

Full details of the total synthesis of phostriecin (2), the assignment of its relative and absolute stereochemistry, and the resultant structural reassignment of the natural product previously represented as sultriecin (1), a phosphate versus sulfate mono

Polyketide assembly by alkene-alkyne reductive cross-coupling: Spiroketals through the union of homoallylic alcohols

A reaction sequence composed of regioselective formal hydroalkynylation, reductive ene-yne cross-coupling, and oxidative cyclization has been developed to prepare stereochemically dense spiroketals. Overall, the chemistry defines a three-component coupling process for the union of two homoallylic alcohol-based substrates with trimethylsilylacetylene.