935509-71-0

Basic information

• Product Name: [Ag(trifluoroacetate)(PPh₃)(bis(2-pyridyl)amine)]
• CAS NO: 935509-71-0
• Molecular Weight: 654.377
• Mol File: 935509-71-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ag(trifluoroacetate)(PPh₃)(bis(2-pyridyl)amine)](CAS DataBase Reference)
• NIST Chemistry Reference: [Ag(trifluoroacetate)(PPh₃)(bis(2-pyridyl)amine)](935509-71-0)
• EPA Substance Registry System: [Ag(trifluoroacetate)(PPh₃)(bis(2-pyridyl)amine)](935509-71-0)

Safety Data

• Hazardous Substances Data: 935509-71-0(Hazardous Substances Data)

Upstream product

• 1202-34-2 di(pyridin-2-yl)amine 
• 2966-50-9 silver trifluoroacetate 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

Synthesis and structural characterization of adducts of silver(I) carboxylate salts AgX (X = CF3COO, CH3COO) with ER3 (E = P, As; R = Ph, cy, o-tolyl) and oligodentate aromatic bases derivative of 2,2′-bipyridyl, L, AgX:PR3:L (1:1:1)

Twenty-one adducts of the form AgX:ER3:L (1:1:1) (X = CF3COO ('tfa'), CH3COO ('ac'), E = P, As; R = Ph, cy, o-tolyl; L = 2,2′-bipyridyl ('bpy')-based ligand) have been synthesized and characterized by analytical, spectroscopic (IR, far-IR, 1H, 19F and 31P NMR) and single crystal X-ray diffraction studies. The resulting complexes are predominantly of the form [(R3E)AgL]+X-, with a trigonal EAgN2 coordination environment, the planarity of which may be perturbed by the approach of anion or solvent. The carboxylate anions have been found to be uni-, or semi-bidentate, or also completely ionic, as in the complexes [Ag(PPh3)(bpy)(H2O)](tfa) and [Ag(PPh3)(dpk · H2O)](tfa) ('dpk · H2O' = bis(2-pyridyl)ketone (hydrated)). The complexes Agac:PPh3:dpa (1:1:1) and Agac:P(o-tol)3:dpa:MeCN (1:1:1:1) are dinuclear, with bridging unidentate acetate and terminal unidentate dpa ('dpa' = bis(2-pyridyl)amine).