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935532-09-5

diphenylethynylphosphine-borane complex is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 935532-09-5 Structure

  • Basic information

    1. Product Name: diphenylethynylphosphine-borane complex
    2. Synonyms: diphenylethynylphosphine-borane complex
    3. CAS NO:935532-09-5
    4. Molecular Formula:
    5. Molecular Weight: 224.05
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 935532-09-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: diphenylethynylphosphine-borane complex(CAS DataBase Reference)
    10. NIST Chemistry Reference: diphenylethynylphosphine-borane complex(935532-09-5)
    11. EPA Substance Registry System: diphenylethynylphosphine-borane complex(935532-09-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 935532-09-5(Hazardous Substances Data)

935532-09-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 935532-09-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 9,3,5,5,3 and 2 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 935532-09:
(8*9)+(7*3)+(6*5)+(5*5)+(4*3)+(3*2)+(2*0)+(1*9)=175
175 % 10 = 5
So 935532-09-5 is a valid CAS Registry Number.

935532-09-5Relevant articles and documents

Silyl alkynylphosphine-boranes: Key precursors of triazolylphosphines via tandem desilylation-Click chemistry

Veillard, Romain,Bernoud, Elise,Abdellah, Ibrahim,Lohier, Jean-Francois,Alayrac, Carole,Gaumont, Annie-Claude

supporting information, p. 3635 - 3640 (2014/06/09)

A versatile synthesis of 1,2,3-triazolyl-4-phosphines from the borane complexes of phosphino-alkynes is reported. The efficiency of the procedure relies on the use of readily available silyl-protected alkynylphosphine-boranes, which were subjected to desilylation with TBAF followed by copper-catalyzed azide-alkyne-cycloaddition in one pot. Subsequent treatment with DABCO afforded the targeted triazolylphosphines in high yields. The reported method was applied to the synthesis of the first example of an enantioenriched P-stereogenic triazolylphosphine (98.8% ee). This journal is the Partner Organisations 2014.

Synthesis of Z-alkenyl phosphorus compounds through hydroalumination and carbocupration of alkynyl precursors

Ortial, Stephanie,Montchamp, Jean-Luc

supporting information; experimental part, p. 3134 - 3137 (2011/07/31)

The stereocontrolled synthesis of Z-alkenylphosphine-borane complexes is easily accomplished via the hydroalumination or carbocupration of alkynyl precursors. Z/E ratios are generally higher than 95/5. These reactions are stereocomplementary to our olefination approach.

Modifiable bidentate systems via N-C rearrangement in triazoles

Smith, Elana A. Slutsky,Molev, Gregory,Botoshansky, Mark,Gandelman, Mark

supporting information; experimental part, p. 319 - 321 (2011/03/17)

A new N-C rearrangement of substituted triazoles has been discovered. This process has been applied to the synthesis of diverse classes of mixed bidentate ligands and their metal complexes with highly modifiable backbones, including the first bisphosphine

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