93554-12-2Relevant academic research and scientific papers
PHOSPHA-ANALOGE SN2'-ALLYLUMLAGERUNG
Karsch, Hans H.,Reisacher, Hans-Ulrich
, p. 203 - 206 (2007/10/02)
The Z-isomer of Ar-P=CH-P(OtBu)Ar (Ar=2.4.6-tBu3C6H2) is formed from the E-1.3 diphosphaallylchloride Ar-P=CH-P(Cl)Ar and KOtBu at low temperature via a SN2' allyl rearrangement and transformed to the E-isomer thermally.
C-PHOSPHINOSUBSTITUIERTE PHOSPHAALKENE UND EIN ERSTES CARBODIPHOSPHAN
Karsch, Hans H.,Koehler, Frank H.,Reisacher, Hans-Ulrich
, p. 3687 - 3690 (2007/10/02)
A series of novel phosphoalkenes, Yosh-P=CH-P(X)R (Yosh = 2,4,6-t-Bu3C6H2) has been prepared, as well as the first stable carbodiphosphane, Yosh-P=C=P-Yosh, which has been characterized by elemental analysis, NMR and mass spectroscopy.
