93555-64-7

Basic information

• Product Name: {(OC)3Mo(((C₆H₅)2P)2CH₂)2Ir(CO)(NCC₆H₅)}⁽¹⁺⁾*PF₆^(1-)={(OC)3Mo(((C₆H₅)2P)2CH₂)2Ir(CO)(NCC₆H₅)}PF₆
• CAS NO: 93555-64-7
• Molecular Weight: 1417.08
• Mol File: 93555-64-7.mol

Chemical Properties

• CAS DataBase Reference: {(OC)3Mo(((C₆H₅)2P)2CH₂)2Ir(CO)(NCC₆H₅)}⁽¹⁺⁾*PF₆^(1-)={(OC)3Mo(((C₆H₅)2P)2CH₂)2Ir(CO)(NCC₆H₅)}PF₆(CAS DataBase Reference)
• NIST Chemistry Reference: {(OC)3Mo(((C₆H₅)2P)2CH₂)2Ir(CO)(NCC₆H₅)}⁽¹⁺⁾*PF₆^(1-)={(OC)3Mo(((C₆H₅)2P)2CH₂)2Ir(CO)(NCC₆H₅)}PF₆(93555-64-7)
• EPA Substance Registry System: {(OC)3Mo(((C₆H₅)2P)2CH₂)2Ir(CO)(NCC₆H₅)}⁽¹⁺⁾*PF₆^(1-)={(OC)3Mo(((C₆H₅)2P)2CH₂)2Ir(CO)(NCC₆H₅)}PF₆(93555-64-7)

Safety Data

• Hazardous Substances Data: 93555-64-7(Hazardous Substances Data)

Upstream product

• 100-47-0 benzonitrile 

Relevant articles and documents

Some Chemistry of the Heterobimetallic Complexes and PF6 (M = Rh or Ir, dppm = Ph2PCH2PPh2). Structure of CMe)Rh(CO)>

The previously described complex (1a) does not readily undergo metathesis, thus when treated with NaI it gave in only ca. 50percent yield even after 3 h.However, the salt PF6 (2a) when treated with NH4Br, NH4I, NaN3, or NaCN gave complexes of type (X = Br, I, N3, or CN) in good yield. 31P- N.m.r. evidence suggests that occurs in two forms, a major form analogous to (1a) and a minor form (3) which possibly has a semibridging CO.Complex (1a) or (2a) reacts with NaBH4 to give a hydrido complex .Treatment of (2a) with Li(CCR) gave the acetylide comlexes CR)Rh(CO)> (R = Me, Ph, or C6H4Me-p) (4a)-(4c).Treatment of (1a) or (2a) with MeCN in the presence of PF6- gave the complex PF6.The previously described Pf6 react similarly with NCR (R = Me or Ph) to give the analogous nitrile complexes PF6.Treatment of (1a) or (2a) with ButNC gives t)>+.Crystals of the compound CMe)Rh(CO)> are triclinic, space group P, with a = 1802.2(3), b = 1303.2(3), c = 1228.2(3) pm, α = 114.77(2), β = 97.52(2), γ = 102.02(2) degree, and Z = 2; final R'factor 0.037 for 6006 observed reflections.The structure shows that the two metal centres are asymmetrically bridged by methylacetylide which forms a ? bond to rhodium and a side-on ? bond to molybdenum.