935697-14-6

Upstream product

• 54211-14-2 7-methylenebicyclo<4.1.0>heptane 
• 200010-86-2 2-(methyldiphenylsilyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Downstream Products

• 935697-23-7 (1S,2S)-2-acetyl-1-(methyldiphenylsilyl)cyclohexane 
• 935697-24-8 cis-1-((1R,2S)-2-hydroxycyclohexyl)ethan-1-one 
• 140630-67-7 trans-1-(2-hydroxycyclohexyl)ethanone 

Relevant academic research and scientific papers

Chirality-Amplifying, Dynamic Induction of Single-Handed Helix by Chiral Guests to Macromolecular Chiral Catalysts Bearing Boronyl Pendants as Receptor Sites

Helical chirality of poly(quinoxaline-2,3-diyl)s bearing a boronyl pendant at the 5-position of the quinoxaline ring was induced by condensation with chiral guests such as a diol, diamine, and amino alcohol. Reversible induction of a single-handed helical

Enhanced catalyst activity and enantioselectivity with chirality-switchable polymer ligand PQXphos in Pd-catalyzed asymmetric silaborative cleavage of meso -methylenecyclopropanes

The poly(quinoxaline-2,3-diyl)-based helically chiral phosphine ligands PQXphos exhibited high enantioselectivities up to 97% ee in palladium-catalyzed desymmetrization of meso-1,2-dialkylsubstituted-3-methylenecyclopropanes through silaborative cleavage

Kinetic resolution of racemic 1 -alkyl-2-methylenecyclopropanes via palladium-catalyzed silaborative C-C cleavage

Kinetic resolution of racemic 1-alkyl-2-methylenecyclopropanes via silaborative C-C cleavage was efficiently catalyzed by a palladium complex bearing a chiral phosphoramidite, affording 2-boryl-3-silylmathy 1-1 -alkenes as major products with up to 92% ee

Palladium-catalyzed asymmetric silaborative C-C cleavage of meso-methylenecyclopropanes

An enantioselective silaborative C-C cleavage of meso-methylenecyclopropanes (meso-MCPs) was achieved by using a palladium catalyst bearing a chiral monodentate phosphine ligand. The (R)-2-bis(3,5-dimethylphenyl)phosphino-1,1′-binaphthyl gave the highest