936005-47-9Relevant academic research and scientific papers
Enantio- and diastereomerically pure decalins by deslongchamps-type annulation of dienolates containing a chiral lactone substituent
Tricotet, Thomas,Brueckner, Reinhard
, p. 1069 - 1074 (2008/02/08)
A conceptionally novel 1,3-asymmetric induction has been established. It controls the relative and absolute configuration of up to 5 stereocenters. They emerge from the anionic Diels-Alder reactions ("Deslongchamps ambulations") between oxocyclohexenecarb
