936016-88-5

Basic information

• Product Name: 6-benzenesulfonyl-2-(1,6-bis-triisopropylsilanyloxy-hex-3-enyl)-3-methyl-tetrahydro-pyran
• Synonyms: 6-benzenesulfonyl-2-(1,6-bis-triisopropylsilanyloxy-hex-3-enyl)-3-methyl-tetrahydro-pyran
• CAS NO: 936016-88-5
• Molecular Weight: 667.154
• Mol File: 936016-88-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-benzenesulfonyl-2-(1,6-bis-triisopropylsilanyloxy-hex-3-enyl)-3-methyl-tetrahydro-pyran(CAS DataBase Reference)
• NIST Chemistry Reference: 6-benzenesulfonyl-2-(1,6-bis-triisopropylsilanyloxy-hex-3-enyl)-3-methyl-tetrahydro-pyran(936016-88-5)
• EPA Substance Registry System: 6-benzenesulfonyl-2-(1,6-bis-triisopropylsilanyloxy-hex-3-enyl)-3-methyl-tetrahydro-pyran(936016-88-5)

Safety Data

• Hazardous Substances Data: 936016-88-5(Hazardous Substances Data)

Upstream product

• 153495-48-8 but-3-ynyloxy-triisopropyl-silane 
• 88424-94-6 (1R,2R)-2-methyl-1-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-ol 
• 936016-85-2 1-(3-methyl-3,4-dihydro-2H-pyran-2-yl)-6-triisopropylsilanyloxy-hex-3-en-1-ol 
• 936016-86-3 2-(1,6-bis-triisopropylsilanyloxy-hex-3-enyl)-3-methyl-3,4-dihydro-2H-pyran 
• 618-41-7 Benzenesulfinic acid 
• 936016-77-2 4-(1-allyloxy-2-methyl-but-3-enyl)-2,2-dimethyl-[1,3]dioxolane 
• 936016-83-0 (4-iodo-but-3-enyloxy)-triisopropyl-silane 
• 936016-78-3 2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-3-methyl-3,6-dihydro-2H-pyran 
• 936016-79-4 1-(3-methyl-3,6-dihydro-2H-pyran-2-yl)-ethane-1,2-diol 
• 936016-84-1 3-methyl-2-oxiranyl-3,4-dihydro-2H-pyran 
• 936016-80-7 3-methyl-2-oxiranyl-3,6-dihydro-2H-pyran 

Relevant articles and documents

A reductive cyclization approach to attenol A

A reductive cyclization strategy was applied to the synthesis of attenol A. This nontraditional approach to the spiroacetal structure illustrated several advantages of the reductive cyclization methodology. The attenol A core was formed in a carbon-carbon bond coupling that gave rise to a previously inaccessible spiroacetal epimer, a new method to synthesize thioketene acetals from a phenyl sulfone was realized, and the configurational stability of a nonanomeric spiroacetal was evaluated. A minor byproduct in the reductive cyclization reaction was identified that for the first time allowed direct evaluation of the stereoselectivity in a reductive cyclization of a dialkyloxy alkyllithium reagent.