93605-95-9Relevant academic research and scientific papers
DIELS-ALDER CYCLIZATION OF 2,8,10-UNDECATRIENALS AS A ROUTE TO 1,2,3,4,4a,5,6,8a-OCTAHYDRONAPHTHALENES
Marshall, James A.,Audia, James E.,Grote, Jonathan,Shearer, Barry G.
, p. 2893 - 2902 (2007/10/02)
2,8,10-Undecatrienals have been found to undergo facile Diels-Alder cyclization upon treatment with alkylaluminum chlorides in methylene chloride at low temperature.The reaction is highly endo-selective.Protected alcohol substituents at the C-4 and C-7 po
Intramolecular Diels-Alder Cyclization of Conjugated Aldehydes. Synthesis of a Chlorothricolide Intermediate
Marshall, James A.,Audia, James E.,Grote, Jonathan
, p. 5277 - 5279 (2007/10/02)
Various substituted 2,8,10-undecatrienals have been found to undergo facile intramolecular Diels-Alder cyclization in the presence of dialkylaluminium chlorides to give bicyclooctahydronaphthalenecarboxaldehydes with high endo selectivity.The metho
