936112-19-5Relevant academic research and scientific papers
Triazole-fused sugars from nitroalkene-containing C-glycosides by a tandem 1,3-dipolar cycloaddition and intramolecular Michael addition
Zou, Wei,Bhasin, Milan,Vembaiyan, Kannan,Williams, Dean T.
scheme or table, p. 1024 - 1027 (2009/09/05)
A synthetic method to triazole-fused sugars by treatment of nitroalkene-containing C-glycosides with sodium azide is described. Initial experiments conducted at room temperature gave only the 1,3-dipolar cycloaddition products. However, at elevated reacti
Polyhydroxylated indolines and oxindoles from C-glycosides via sequential Henry reaction, Michael addition, and reductive amination/amidation
Zou, Wei,Wu, An-Tai,Bhasin, Milan,Sandbhor, Mahendra,Wu, Shih-Hsiung
, p. 2686 - 2689 (2007/10/03)
6-Nitro-2′-carbonyl-C-glycofuranosides synthesized via Henry reaction from 1-C-allyl 5-aldo-C-glycoside underwent an intramolecular Michael addition to afford nitrocyclohexanol derivatives in good to excellent yield. Reduction of the nitro group followed
