936253-22-4

Basic information

• Product Name: PtMe₂(κ²-N,N-2-C₅H₄NCH=NPh)
• CAS NO: 936253-22-4
• Molecular Weight: 407.374
• Mol File: 936253-22-4.mol

Chemical Properties

• CAS DataBase Reference: PtMe₂(κ²-N,N-2-C₅H₄NCH=NPh)(CAS DataBase Reference)
• NIST Chemistry Reference: PtMe₂(κ²-N,N-2-C₅H₄NCH=NPh)(936253-22-4)
• EPA Substance Registry System: PtMe₂(κ²-N,N-2-C₅H₄NCH=NPh)(936253-22-4)

Safety Data

• Hazardous Substances Data: 936253-22-4(Hazardous Substances Data)

Upstream product

• 7032-25-9 2-(phenyliminomethyl)pyridine 
• 79870-64-7 [Pt2Me4(μ-SMe2)2] 

Relevant articles and documents

Quinone methide generation based on a cis-(N,N) platinum complex

Quinone methides (QMs) are highly reactive compounds that play important roles in various chemical and biological processes. In this work, a stable imino-pyridine platinum(IV) complex that bears a silylprotected oxy-benzyl precursor of the quinone methide BHT - QM, derived from the food preservative 2,6-di-tert-butyl-4-metnylphenol (BHT), was prepared and fully characterized, including by X-ray structural characterization. De-silylation results in a rarely observed, fully characterized, zwitterionic intermediate η1-methylene-p-phenoxy-Pt(IV), which undergoes de-aromatization to the unstable BHT - QM, which was trapped in solution.

A biomimetic phenol substituent effect on the reaction of a dimethylplatinum(ii) complex with oxygen: Proton coupled electron transfer and multiple proton relay

The complex [PtMe2({κ2-N,N-RNCH-2-C5H4N})] reacts with oxygen in acetone solution to give the platinum(iv) complex [Pt(OH)Me2{κ3-N,N,O-RNH-CH(2-C5H4N)(CHCMeO)}], when