93626-92-7

Basic information

• Product Name: (2E)-3-(4-chlorophenyl)acrylaldehyde O-methyl oxime
• Synonyms: (2E)-3-(4-chlorophenyl)acrylaldehyde O-methyl oxime
• CAS NO: 93626-92-7
• Molecular Weight: 195.648
• Mol File: 93626-92-7.mol

Chemical Properties

• CAS DataBase Reference: (2E)-3-(4-chlorophenyl)acrylaldehyde O-methyl oxime(CAS DataBase Reference)
• NIST Chemistry Reference: (2E)-3-(4-chlorophenyl)acrylaldehyde O-methyl oxime(93626-92-7)
• EPA Substance Registry System: (2E)-3-(4-chlorophenyl)acrylaldehyde O-methyl oxime(93626-92-7)

Safety Data

• Hazardous Substances Data: 93626-92-7(Hazardous Substances Data)

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 1075-77-0 4-chlorocinnamaldehyde 
• 593-56-6 N-methoxylamine hydrochloride 

Downstream Products

• 1073-67-2 4-vinylbenzyl chloride 
• 612-61-3 7-chloroquinoline 
• 28446-72-2 (2E)-3-(4-chlorophenyl)acrylonitrile 

Relevant articles and documents

Highly γ-Regioselective 1,2-Addition of α,β-Unsaturated Oxime Ethers with Allylzinc Bromides: A Straightforward Approach for the Synthesis of Homoallylic Amines

A highly regioselective reaction between allylzinc bromide reagents and α,β-unsaturated oxime ethers for the one-step synthesis of the homoallylic amines is reported. This process is a regioselective 1,2-addition reaction providing a new γ-position with carbon-carbon bond formation. Furthermore, the reaction substrates are widely applicable and can be produced in a high yield.

Thermolysis of Polyazapentadienes. Part 7. An Unambiguous Route to 7-Substituted Quinolines from Cinnamaldehyde Derivatives

Flash vacuum pyrolysis of the cinnamaldehyde phenylhydrazone derivatives (4) - (6) or O-alkyl oxime derivatives (7) - (12) at 600 -650 deg C and 10-2 - 10-3 Torr leads to approximately equal quantities of cinnamonitriles and quinolines.Use of a p-substituted cinnamaldehyde derivatives gives the appropriate 7-substituted quinoline in high isomeric purity; the reactions take place via conjugated iminyl radicals.