93626-99-4

Basic information

• Product Name: 2,4-Hexadien-1-one, 3-methyl-1-phenyl-
• CAS NO: 93626-99-4
• Molecular Formula: C13H14O
• Molecular Weight: 186.254
• Mol File: 93626-99-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,4-Hexadien-1-one, 3-methyl-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Hexadien-1-one, 3-methyl-1-phenyl-(93626-99-4)
• EPA Substance Registry System: 2,4-Hexadien-1-one, 3-methyl-1-phenyl-(93626-99-4)

Safety Data

• Hazardous Substances Data: 93626-99-4(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 72006-12-3 3-methyl-hexa-2,4-dienoyl chloride 

Downstream Products

• 93627-06-6 3,5-dimethyl-7-phenyl-3H-1,2-diazepine 
• 93627-03-3 6,7-dihydro-5,7-dimethyl-3-phenyl-1-tosyl-1,2-diazepine 

Relevant articles and documents

Δ3-DIHYDROPYRANS AND TETRAHYDROPYRANS BY REDUCTION OF PYRYLIUM SALTS WITH SODIUM BOROHYDRIDE IN ACETIC ACID

The major reduction products with triacetoxyborohydride (NaBH4 in AcOH) of 2,4,6-trisubstituted pyrylium salts bearing alkyl substituents in the 2- and/or 6-position are the Δ3-dihydropyrans with cis 2- and 6-substituents and all-cis-2,4,6-trisubstituted tetrahydropyrans. Δ3-dihydropyrans are shown to be formed via 2H-pyrans by a 1,4 reduction while tetrahydropyrans result from 4H-pyrans by reduction of both enol-ether double bonds.