93629-30-2Relevant academic research and scientific papers
PRACTICAL SYNTHESIS AND POLYMERIZATION OF TRIFLUOROVINYLSILANES. A POSSIBLE PRECURSOR OF POLY(DIFLUOROACETYLENE)
Hiyama, Tamejiro,Nishide, Kiyoharu,Obayashi, Michio
, p. 1765 - 1768 (1984)
An improved procedure for the preparation of trifluorovinylsilanes was established which involved addition of butyllithium to a mixture of chlorosilanes and commercially readily available chlorotrifluoroethylene at -78 to -130 deg C, and the resulting monomer was polymerized with a catalyst such as CsF or (R2N)3S(1+)*F2SiMe3(1-) to give black metallic polymer which showed conductivity of 1E-9 to 1E-10 Ω-1cm-1.
Process for the preparation of a trifluorovinylsilane, and fluorine-containing polymer and process for its preparation
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, (2008/06/13)
A process for preparing a trifluorovinylsilane represented by the general formula: where each R independently represents an alkyl group, an aryl group or an aralkyl group, and n is an integer of 1 to 4, which comprises the reaction of chlorotrifluoroethyl
