93634-87-8

Usage

Uses

Used in Coordination Chemistry:
T-BUTYLDICYCLOHEXYLPHOSPHINE is used as an organophosphine ligand for its strong binding affinity to metal ions, which is essential in the formation of stable metal complexes and contributes to the advancement of coordination chemistry.
Used in Catalysis Applications:
In catalysis, T-BUTYLDICYCLOHEXYLPHOSPHINE is used as a ligand to enhance the catalytic activity and selectivity of metal catalysts, facilitating various chemical reactions with improved efficiency and yield.
Used in the Synthesis of Metal and Metalloid Clusters:
T-BUTYLDICYCLOHEXYLPHOSPHINE is used as a stabilizing agent and modifier in the synthesis of metal and metalloid clusters, ensuring the formation of well-defined structures with specific properties that are valuable in material science and nanotechnology.
Used in the Development of New Materials:
This chemical compound is utilized in the development of new materials, where its ability to interact with metal ions aids in creating materials with tailored properties for specific applications in various industries.
Used in Research and Development:
T-BUTYLDICYCLOHEXYLPHOSPHINE is used in research and development settings to explore its potential applications in creating new catalysts and materials, further expanding its utility in scientific discovery and innovation.

InChI:InChI=1/C16H31P/c1-16(2,3)17(14-10-6-4-7-11-14)15-12-8-5-9-13-15/h14-15H,4-13H2,1-3H3

Upstream product

• 1329620-49-6 dicyclohexyl(1,1-dimethylethyl)phosphine-trihydridoboron 
• 594-19-4 tert.-butyl lithium 
• 16523-54-9 chlorodicyclohexylphosphane 

Downstream Products

• 222055-10-9 Dicyclohexyl-(3-phenylpropyl)phosphine 
• 306308-11-2 dicyclohexyl(2-(4-phenyl)butyl)phosphine 
• 1329620-49-6 dicyclohexyl(1,1-dimethylethyl)phosphine-trihydridoboron 
• 454204-93-4 [Pd(P(C₆H₁₁)2C(CH₃)3)2] 
• 1239667-55-0 [(Cy)2(t-Bu)PH][HB(p-C₆F₄H)3] 
• 851368-22-4 Pd(OAc)2(P(Cy)2(CMe₃))2 
• 222055-11-0 dicyclohexyl(3-(3,5-dimethyl)phenylpropyl)-phosphine 

Relevant academic research and scientific papers

A Lewis Base Nucleofugality Parameter, NFB, and Its Application in an Analysis of MIDA-Boronate Hydrolysis Kinetics

The kinetics of quinuclidine displacement of BH3 from a wide range of Lewis base borane adducts have been measured. Parameterization of these rates has enabled the development of a nucleofugality scale (NFB), shown to quantify and predict the leaving group ability of a range of other Lewis bases. Additivity observed across a number of series R′3-nRnX (X = P, N; R′ = aryl, alkyl) has allowed the formulation of related substituent parameters (nfPB, nfAB), providing a means of calculating NFB values for a range of Lewis bases that extends far beyond those experimentally derived. The utility of the nucleofugality parameter is explored by the correlation of the substituent parameter nfPB with the hydrolyses rates of a series of alkyl and aryl MIDA boronates under neutral conditions. This has allowed the identification of MIDA boronates with heteroatoms proximal to the reacting center, showing unusual kinetic lability or stability to hydrolysis.

γ-Selective cross-coupling of allylic silanolate salts with aromatic bromides using trialkylphosphonium tetrafluoroborate salts prepared directly from phosphine?borane adducts

The γ-selective, palladium-catalyzed cross-coupling of sodium (Z)-2-butenyldiethylsilanolate with a variety of aromatic bromides is reported. The protocol provides high yields (73-94%) and site selectivity (γ/α, 25:1 → > 99:1) in the coupling of electron-

Synthesis and evaluation of new RuCl2(p-cymene)(ER2R′) and (η1:η6-phosphinoarene)RuCl2 complexes as ring-opening metathesis polymerization catalysts

New RuCl2(p-cymene)(ER2R′) complexes (E = P, As, Sb; R, R′ = H, alkyl, arylalkyl) have been synthesized and used as catalyst precursors for the ring-opening metathesis polymerization (ROMP) of cyclooctene, cyclopentene, and norbornen