93662-69-2

Upstream product

• 88338-58-3 1-tosylnonyl isocyanide 
• 21852-32-4 4-bromomethyl-1,2-dimethoxybenzene 
• 112-13-0 n-decanoyl chloride 
• 91-16-7 1,2-dimethoxybenzene 
• 93662-65-8 3',4'-dimethoxyphenyl-2-tosyl-2-decyl isocyanide 
• 109558-46-5 1-(3,4-dimethoxyphenyl)decan-1-one 

Downstream Products

• 101447-92-1 4-decylpyrocatechol 
• 102375-62-2 2-decyl-4,5-dimethoxy-phenethylamine 
• 112508-26-6 (E)-2-decyl-4,5-dimethoxy-β-nitro-styrene 
• 919800-84-3 4,5-didecylbenzene-1,2-diol 
• 919800-82-1 1,2-didecyl-4,5-dimethoxybenzene 
• 919800-80-9 1-(2-decyl-4,5-dimethoxyphenyl)decan-1-one 
• 102310-49-6 1-(2-decyl-4,5-dimethoxy-phenyl)-ethanone 

Relevant academic research and scientific papers

A template-free approach to nanotube-decorated polymer surfaces using 3,4-phenylenedioxythiophene (PhEDOT) monomers

In this work, novel 3,4-phenylenedioxythiophene (PhEDOT) monomers with alkyl, branched, and aromatic substituents were synthesized and tested for their efficacy at forming surfaces with unique wetting properties and surface morphology without the aid of surfactants. Monomers with a naphthalene substituent clearly showed the highest capacity to stabilize gas bubbles (O2 or H2) formed in solution during electrodeposition from trace water, resulting in the formation of nanotubes. Variation in the resulting density, diameter, and height of nanotubes was demonstrated by varying the electropolymerization protocol, conditions, or electrolyte used. The wetting induced by the nanotube formation results in the surfaces formed having both high contact angles with water (W) and strong adhesion, despite all polymers being intrinsically hydrophilic. This one-step and easily tunable approach to nanotube formation has potential to advance applications in membrane design, water transport and harvesting, as well as sensor design.

Supramolecular fibers and microbelts from a phthalhydrazide derivative of crown ether with alkyl chains

Assemlbing behaviors of some crown ether derivatives with alkyl chains were investigated. It was found that a phthalhydrazide derivative was unique among them in that it assembles into fibers in solution, which transform into microbelts on the surface of

A CONVENIENT REDUCTION OF ALKYLATED TOSYLMETHYL ISOCYANIDES: APPLICATIONS FOR THE SYNTHESIS OF NATURAL PRODUCTS

A convenient and simple method for the reduction of mono- and dialkylated tosylmethyl isocyanides with lithium in liquid ammonia to corresponding hydrocarbons is described.The utility of this methodology adopted in the synthesis of tricos-9Z-ene (7g), a sex pheromone of common house fly, (-)-1S,5R,7S-exo-brevicomin (17), an antipode of sex pheromone of Western pine beetle and (4S,5S)-5-hydroxy-4-decanolide (L-factor, 19), a proposed autoregulator for leukaemomycin biosynthesis.

A CONVENIENT REDUCTION OF DIALKYLATED TOSYLMETHYL ISOCYANIDE

Dialkylated tosylmethyl isocyanides have been conveniently reduced to the corresponding hydrocarbons with lithium in liquid ammonia.This process has been succesfully utilised in the synthesis of (Z)-9-tricosene - a sex pheromone of common house fly.